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根据文献资料及实践经验，本公司总结出主要经典反应及其适用贵金属催化剂的关联结果，如下表所示：
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反应式 |
适用催化剂 |
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Pd(PPh3)4 cis-PtCl2(PPh3)2 RhCl(CO)(PPh3)2 trans-PdCl2(PPh3)2 |
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trans-PdCl2(PPh3)2 RhI3 |
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trans-PdCl2(PPh3)2 Pd(PPh3)4 [Pd(OAc)2]3 |
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trans-PdCl2(PPh3)2 Pd(PPh3)4 |
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trans-PdCl2(PPh3)2 [Pd(OAc)2]3 |
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trans-PdCl2(PPh3)2
[Pd(OAc)2]3 |
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[Pd(OAc)2]3 |
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[Pd(OAc)2]3 |
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[Pd(OAc)2]3 |
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[Pd(OAc)2]3 |
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PdCl2 |
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PdCl2 [Pd(OAc)2]3 |
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Pd(PPh3)4
[Pd(OAc)2]3 |
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[Pd(OAc)2]3 |
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PdCl2 |
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trans-PdCl2(PPh3)2
[Pd(OAc)2]3 |
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Pd(PPh3)4 [Pd(OAc)2]3 |
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trans-PdCl2(PPh3)2 Pd(PPh3)4 [Pd(OAc)2]3 |
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[Pd(OAc)2]3 |
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trans-PdCl2(PPh3)2 Pd(PPh3)4 PdCl2(Ph2PCH2CH2PPh2) |
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[Pd(OAc)2]3 |
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trans-PdCl2(PPh3)2 Pd(PPh3)4 [Pd(OAc)2]3 |
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[PdCl2(Ph2PCH2CH2CH2CH2PPh2)]
trans-PdCl2(PPh3)2
Pd(PPh3)4 PdCl2(Ph2PCH2CH2PPh2) |
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trans-PdCl2(PPh3)2 Pd(PPh3)4 |
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[Pd(OAc)2]3 |
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trans-PdCl2(PPh3)2 |
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trans-PdCl2(PPh3)2
[Pd(OAc)2]3 |
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Pd(PPh3)4 [Pd(OAc)2]3 |
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[Pd(OAc)2]3 [Rh(CH3CO2)2]2 [Rh(C8H15O2)2]2 |
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RhCl(PPh3)3 |
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[Pd(OAc)2]3 |
|
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10% Pd/C |
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5%Pd/C |
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5%Pd/C |
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5%Pd/C |
|
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trans-PdCl2(PPh3)2
[Pd(OAc)2]3 |
|
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RhH(CO)(PPh3)3 Rh(C5H7O2)(CO)(PPh3) Rh(C5H7O2)(CO)2 |
|
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RhCl(PPh3)3 |
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Pd/ C BaSO4,CaCO3 |
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Pd/ C |
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5% Pd/ CaCO3 |
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Pt/C>Rh/C>Pd/C |
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5% Pd/ Al2O3 |
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5% Pt/C |
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5%Pd/C |
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5%Pd/C |
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5%Pd/C |
|
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5% Rh/C |
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5%Pd/C 1% Pd/ Al2O3 |
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5% Rh/C |
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5% Pt/C |
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5% Rh/C |
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5% Rh/C |
|
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5% Pt/C |
|
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5% Ru/C |
|
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5% Pt/Graphite |
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5%Pd/C |
|
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5% Ru/C |
|
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5% Pt/C |
|
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5%Pd/C |
|
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5%Pd/C |
|
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5% Ru/C |
|
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1% Pt/C |
|
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RhCl(PPh3)3 |
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5% Pt/C |
|
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5% Pt/C |
|
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5%Pd/C |
|
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5% Rh/C |
|
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5%Pd/C |
|
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5%Pd/C |
|
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5% Pt/C |
|
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5%Pd/C |
|
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5%Pd/C |
|
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5%Pd/C |
|
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5%Pd/C |
|
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1% Pt/C |
|
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2% Pt/C |
|
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5%Pd/C |
|
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5%Pd/C |
|
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5%Pd/C |
|
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5%Pd/C |
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5%Pd/C |
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5% Rh/C |
|
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5%Pd/C |
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5%Pd/C 5% Pt/C |
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5%Pd/C 5% Pt/C |
|
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5%Pd/C |
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5%Pd/C |
|
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5%Pd/C |
|
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5% Ru/C |
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5%Pd/C |
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RhCl(PPh3)3 |
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RuCl2(PPh3)3 |
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RuCl2(PPh3)3 |
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5% Ru/C 5% Pt/C |
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5% Ru/C 5% Pt/C |
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5% Pt/C |
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[Pd(OAc)2]3 |
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RuCl2(PPh3)3 |
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PdCl2 |
具体使用条件请咨询本公司研发中心 。版权所有未经允许请勿转载使用。返回顶部
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